Removal of Arsenic (III) from groundwater applying a reusable Mg-Fe-Cl layered double hydroxide

BACKGROUND: Layered double hydroxide compounds (LDHs) have been applied for the removal of oxyanions including arsenate (As(V)). However, the aim of this present research is to develop a LDH to treat arsenite (As(III)). Both batch and column sorption studies were conducted to assess the effect of LDH dosage, contact time, solution pH and initial As(III) concentrations on the As(III) removal performance. The potential re-use of this sorbent was also investigated.<p></p> RESULTS: For 2 g L−1 of Mg-Fe-Cl LDH, As(III) in test solution can be reduced from 400 µg L−1 to <10 µg L−1 after a contact time of 2 h. High As(III) concentration in Bangladesh groundwater can be reduced to meet the national drinking water standards (<50 µg L−1). The maximum adsorption capacity of As(III) by Mg-Fe-Cl LDH is 14.6 mg g−1-LDH. Further, reusability of this sorbent was at least 20 cycles of regeneration with effective As(III) removal between 93.0 and 98.5%. Moreover, As(III) removal was unaffected by the solution pH but affected by the co-existing competing anions and concentration of As(III). Finally, the main mechanism of As(III) removal by Mg-Fe-Cl LDH was suggested to be chemical sorption together with anion and ligand exchange with interlayer Cl− and OH− ions.<p></p> CONCLUSION: High efficiency of sorption of As(III) by the developed Mg-Fe-Cl LDH was demonstrated in this study which is generally not the case for most other sorbent materials. Pilot-scale trials are needed to explore the suitability of full application of the developed Mg-Fe-Cl LDH for the removal of As(III).<p></p&gt

Basis risk and property derivative hedging in the UK : implications of the 2007 IPF Study of tracking error

Thesis (S.M.)--Massachusetts Institute of Technology, Program in Real Estate Development in Conjunction with the Center for Real Estate, 2009.This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections.Cataloged from student submitted PDF version of thesis.Includes bibliographical references (p. 65).This thesis examines how the basis risk affects property derivative hedging in the UK market, based on the tracking error (basis risk) report from the Investment Property Forum study in 2007 (the IPF Study). The thesis first analyzes the risks relevant to hedging and defines the basis risk. Considering hedgers with different objectives measure hedging efficiency differently, this thesis divides the hedging users into two major categories: β-Avoidance hedgers and a-Usage hedgers. Each of these has two sub-ordinate groups. In order to quantify the basis-risk influences on hedging, a Monte Carlo simulation designed for short contract of the swap is used. Basis risks of portfolios with different sizes are selected from the IPF Study. To shed light on different hedging uses, three scenarios are tested based on different assumptions on the expected alpha and leverage. Other relevant elements are also studied, such as the price of the debt and the swap. The analysis results in a useful reference for investors who are interested in eliminating portfolio risks with hedging strategies. In the end, the thesis suggests avenues for the further study.by Jia Ma.S.M

A General Approach for the Exact Solution of the Schrodinger Equation

The Schr\"{o}dinger equation is solved exactly for some well known potentials. Solutions are obtained reducing the Schr\"{o}dinger equation into a second order differential equation by using an appropriate coordinate transformation. The Nikiforov-Uvarov method is used in the calculations to get energy eigenvalues and the corresponding wave functions.Comment: 20 page

Low rank decompositions for sum of squares optimization

Thesis (S.M.)--Massachusetts Institute of Technology, Computation for Design and Optimization Program, 2006.Includes bibliographical references (leaves 77-79).In this thesis, we investigate theoretical and numerical advantages of a novel representation for Sum of Squares (SOS) decomposition of univariate and multivariate polynomials. This representation formulates a SOS problem by interpolating a polynomial at a finite set of sampling points. As compared to the conventional coefficient method of SOS, the formulation has a low rank property in its constraints. The low rank property is desirable as it improves computation speed for calculations of barrier gradient and Hessian assembling in many semidefinite programming (SDP) solvers. Currently, SDPT3 solver has a function to store low rank constraints to explore its numerical advantages. Some SOS examples are constructed and tested on SDPT3 to a great extent. The experimental results demonstrate that the computation time decreases significantly. Moreover, the solutions of the interpolation method are verified to be numerically more stable and accurate than the solutions yielded from the coefficient method.by Jia Li Sun.S.M

Bound state solutions of the Dirac-Rosen-Morse potential with spin and pseudospin symmetry

The energy spectra and the corresponding two- component spinor wavefunctions of the Dirac equation for the Rosen-Morse potential with spin and pseudospin symmetry are obtained. The $s-$wave ($\kappa = 0$ state) solutions for this problem are obtained by using the basic concept of the supersymmetric quantum mechanics approach and function analysis (standard approach) in the calculations. Under the spin symmetry and pseudospin symmetry, the energy equation and the corresponding two-component spinor wavefunctions for this potential and other special types of this potential are obtained. Extension of this result to $\kappa \neq 0$ state is suggested.Comment: 18 page

Efeito do ensacamento dos frutos no controle de pragas e doenças e na qualidade e maturação de maçãs ‘Fuji Suprema’.

O objetivo deste trabalho foi avaliar a eficiência de embalagens de diferentes materiais para a proteção contra pragas e doenças e seu efeito sobre a qualidade físico-química, maturação e teor de cálcio (Ca) em maçãs ‘Fuji Suprema’. O experimento foi desenvolvido nas safras de 2007/2008 e 2008/2009, em pomar manejado sob o sistema orgânico, localizado na região de São Joaquim (SC). O pomar era composto por plantas de dez anos de idade da cultivar Fuji Suprema, sobre porta-enxerto ‘Marubakaido’, com interenxerto ‘EM-9’. Depois do raleio manual, aproximadamente 40 dias após a plena floração, os frutos foram ensacados com embalagens plásticas transparentes microperfuradas ou de tecido não texturizado (TNT). Os frutos foram mantidos ensacados até a colheita. A testemunha foi constituída por frutos não ensacados. Na colheita, os frutos foram avaliados quanto aos danos provocados por mosca-das-frutas (Anastrepha fraterculus), mariposa oriental (Grapholita molesta) e lagarta enroladeira (Bonagota salubricola). As doenças foram avaliadas pela incidência de sarna da macieira (Venturia inaequalis), podridão amarga (Colletotrichum gloeosporioides) e podridão carpelar (Alternaria sp., Fusarium sp.). Também foi avaliada a incidência de distúrbios fisiológicos “russeting” e “bitter pit”, atributos físico-químicos de maturação e qualidade e o teor de Ca nos frutos. Independentemente do tipo de embalagem verificou-se que o ensacamento é prática eficaz na proteção contra o ataque de insetos, mas não reduz a incidência e o desenvolvimento de doenças nos frutos. Na safra de 2008/2009, o ensacamento dos frutos aumentou o teor de Ca e reduziu a incidência de “bitter pit”, e aumentou a incidência do “russeting”. O ensacamento dos frutos antecipou a maturação, especialmente com embalagem plástica transparente microperfurada, e reduziu a coloração vermelha, especialmente com embalagem TNT